- 發布日期：114-10-01
- 發布單位：評估管理組
辨識資料
- 中文名稱：詳如「評估管制方向」項次內容
- 英文名稱：詳如「評估管制方向」項次內容
- 化學文摘社登記號碼：詳如「評估管制方向」項次內容
- 分子式：-
國內外管制現況
- 應用範圍
PFAS(PFOA、PFHxS、LC-PFCA)廣泛應用於各產業及消費產品，包括化學、金屬電鍍、半導體等產業，以及用於不沾鍋及烘培器具、食品包材等產品，可作為防水、防油及防污之保護層。
- 國內管制現況
參據斯德哥爾摩公約及國際管理趨勢，就國內業者登錄之既有及新化學物質比對國際清單，排除已列管或預告之物質，總計對33種全氟己烷磺酸(PFHxS)、22種全氟辛酸(PFOA)及111種長鏈全氟羧酸(LC-PFCA)進行評估列管。
- 國際管制現況
UV-328於持久性有機污染物審查委員會第16次會議(POPRC16)首度由瑞士提案列管，歷經多次會議審查，於2023年COP-11決議將其列入附件A管制，並給予特定豁免條件如下。
|
公約 / 法規 |
清單名稱 |
PFAS 類別 |
管制現況 |
|---|---|---|---|
|
斯德哥爾摩公約 |
附件 A |
PFOA |
斯德哥爾摩公約締約方大會第 9 次會議 (COP-9) 決議將 PFOA 列入公約附件 A 列管，並訂定製造及使用等特定豁免。 |
|
PFHxS |
COP 10 決議將 PFHxS 列入公約附件 A 列管，且無訂定特定豁免。 |
||
|
LC-PFCA （審議中） |
持久性有機污染物審查委員會第 15 次會議 (POPRC 15) 建議締約國大會考慮將其列入公約附件 A 列管，且給予特定豁免條件，將於 2025 年 COP 12 決議是否列管。 |
||
|
化學品註冊、 評估及授權法 (REACH) |
高關注物質 |
PFOA 、 PFHxS |
作濃度大於 0.1% 或年製造、輸入量大於 1 噸，須向歐洲化學品管理局 (ECHA) 通報。 |
|
既有化學物質 |
PFO A 、 PFHxS |
每年製造或輸入化學物質超過 1 噸以上之業者，須對此化學品進行註冊，提供化學物質之特性、用量用途、安全性等各種物質相關資料。 |
|
|
附錄 17 ：限制物質 |
LC-PFCA |
自 2023 年 2 月 25 日起，限制碳鏈長度為 9 到 14 個碳 (C9-C14) 之 PFCA 及其鹽類與相關物質之製造、投放市場、使用；除非物質、混合物或成品中 C9-C14 之 PFCA 及其鹽類總濃度低於 25 ppb ，或 C9-C14 PFCA 相關物質總濃度低於 260 ppb ，並訂有豁免。 |
|
|
PFHxA |
自 2026 年 4 月 10 日起分階段限制投放市場或使用 PFHxA 及其鹽類總濃度 25 ppb 以上；或 PFHxA 相關物質濃度 1,000 ppb ，限制產品包括消費者紡織品、食品包裝、消費者混合物、化妝品以及消防泡沫應用。 |
||
|
鹿特丹公約 |
附件三 |
PFOS 、 PFOA |
締約國間透過禁止或嚴格限制化學物質使用以降低風險。 |
|
持久性有機污染物 (POPs) |
附錄 1 |
PFOA |
禁止或限制製造、投入市場及使用，亦訂定 PFOA 存在於物質、混合物或成品中非蓄意微量污染物之濃度，並有條件豁免半導體製造、攝影底片之塗層、醫療器材等之製造及使用。 |
|
PFHxS |
管理 PFHxS 存在於物質、混合物、成品或消防泡沫中非蓄意微量污染物之濃度。 |
以上國際管制現況僅彙整部分公約法規管制情形，其PFAS於各國皆逐步評估列管中。
評估管制方向
參據斯德哥爾摩公約及國際管理趨勢，就國內業者登錄之既有及新化學物質比對國際清單，排除已列管或預告之物質，總計對33種PFHxS、22種PFOA及111種LC-PFCA進行評估列管。
|
物質 |
最新清單數量 |
目前我國公告數量 |
備註 |
|---|---|---|---|
|
PFHxS |
176 |
147 |
|
|
PFOA |
375 |
353 |
|
|
LC-PFCA |
199 |
84 |
|
|
PFAS |
269 |
0 |
|
-
PFHxS
-
毒性分類及相關運作規定尚在評估。
-
增列PFHxS之33種化學文摘社登記號碼(CAS No.)如下。
|
序號 |
CAS No. |
英文名稱 |
|---|---|---|
|
1 |
1000597-52-3 |
Phosphonium, triphenyl(phenylmethyl)-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
2 |
108427-54-9 |
1-Butanaminium, N,N,N-tributyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
3 |
108427-55-0 |
Ethanaminium, N,N,N-triethyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
4 |
1187817-57-7 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, compd. with pyrrolidine (1:1) |
|
5 |
1310480-24-0 |
Ethanaminium, N-[4-[[4-(diethylamino)phenyl][4-(ethylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-ethyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
6 |
1310480-27-3 |
Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(ethylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
7 |
1310480-28-4 |
Methanaminium, N-[4-[[4-(dimethylamino)phenyl][4-(phenylamino)-1-naphthalenyl]methylene]-2,5-cyclohexadien-1-ylidene]-N-methyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
8 |
144116-10-9 |
Sulfonium, triphenyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
9 |
1462414-59-0 |
Quinolinium, 1-(carboxymethyl)-4-[2-[4-[4-(2,2-diphenylethenyl)phenyl]-1,2,3,3a,4,8b-hexahydrocyclopent[b]indol-7-yl]ethenyl]-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
10 |
153443-35-7 |
Iodonium, diphenyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
11 |
189274-31-5 |
Methanaminium, N,N,N-trimethyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
12 |
202189-84-2 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, compd. with 2-methyl-2-propanamine (1:1) |
|
13 |
213740-81-9 |
Iodonium, bis[4-(1,1-dimethylethyl)phenyl]-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
14 |
2267980-92-5 |
N-(2-Hydroxyethyl)-N,N-dimethyl-3-[(3-sulfopropyl)[(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)sulfonyl]amino]-1-propanaminium |
|
15 |
341035-71-0 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6- tridecafluoro-, gallium salt |
|
16 |
341548-85-4 |
Sulfonium, bis(4-methylphenyl)phenyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
17 |
350836-93-0 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, scandium(3+) salt (3:1) |
|
18 |
38850-51-0 |
1-Propanaminium, N,N,N-trimethyl-3-[[(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)sulfonyl]amino]-, inner salt |
|
19 |
41184-65-0 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, neodymium(3+) salt (3:1) |
|
20 |
41242-12-0 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, yttrium(3+) salt (3:1) |
|
21 |
421555-73-9 |
Sulfonium, (thiodi-4,1-phenylene)bis[diphenyl-, salt with 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonic acid (1:2) |
|
22 |
421555-74-0 |
Iodonium, bis[4-(1,1-dimethylpropyl)phenyl]-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
23 |
425670-70-8 |
Sulfonium, tris[4-(1,1-dimethylethyl)phenyl]-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
24 |
70136-72-0 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, zinc salt (2:1) |
|
25 |
72033-41-1 |
Triethylammonium perfluorohexane sulfonate1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, compd. with N,N-diethylethanamine (1:1) |
|
26 |
910606-39-2 |
Sulfonium, (4-methylphenyl)diphenyl-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
27 |
92011-17-1 |
1-Hexanesulfonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-, cesium salt (1:1) |
|
28 |
911027-68-4 |
[4-(2-methylprop-2-enoyloxy)phenyl]-diphenylsulfanium;1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonate |
|
29 |
866621-50-3 |
bis(2-tert-butylphenyl)iodanium;1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexane-1-sulfonate |
|
30 |
928049-42-7 |
Dibenzo[k,n][1,4,7,10,13]tetraoxathiacyclopentadecinium, 19-[4-(1,1-dimethylethyl)phenyl]-6,7,9,10,12,13-hexahydro-, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonate (1:1) |
|
31 |
115416-67-6 |
1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluoro-1-hexanesulfinic acid |
|
32 |
85520-91-8 |
1,1,2,2,3,3,4,4,5,5,6,6,6-Tridecafluoro-N-[3-(methylamino)propyl]-1-hexanesulfonamide |
|
33 |
87988-56-5 |
N-Ethyl-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-1-hexanesulfonamide |
-
PFOA
-
毒性分類及相關運作規定尚在評估。
-
增列PFOA之22種CAS No.
|
序號 |
CAS No. |
|
|---|---|---|
|
1 |
335-60-4 |
Pentadecafluorooctanal |
|
2 |
335-64-8 |
Perfluorooctanoyl chloride |
|
3 |
222037-87-8 |
Perfluorooctanoyl bromide |
|
4 |
143260-97-3 |
3-(Perfluorononyl)propanoic acid (Also known as 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-nonadecafluorododecanoic acid) |
|
5 |
812-70-4 |
3-Perfluoroheptyl propanoic acid (7:3) (Also known as 2H,2H,3H,3H-perfluorodecanoic acid). |
|
6 |
26650-10-2 |
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl thiocyanate |
|
7 |
27619-90-5 |
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecane-1-sulfonyl chloride |
|
8 |
142010-50-2 |
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl isocyanate |
|
9 |
42977-21-9 |
Bis(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl) disulfide |
|
10 |
89373-67-1 |
4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoroundecanoyl chloride |
|
11 |
94159-88-3 |
4-(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-Heptadecafluorononyl)-2,2-dimethyl-1,3-dioxolane |
|
12 |
852527-61-8 |
4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-Heptadecafluoroundecyl azide |
|
13 |
36390-05-3 |
(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl)propanedioic acid |
|
14 |
167289-73-8 |
9-Octadecenoic acid (9Z)-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl ester |
|
15 |
253683-00-0 |
Butanedioic acid, monopolyisobutylene derivs., 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl ester |
|
16 |
125768-41-4 |
(Z)-(Perfluorodecyl)ethyl 9-octadecenoate |
|
17 |
254889-67-3 |
1-Decanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-, reaction products with [(trimethylsilyl)oxy]-modified silica |
|
18 |
121065-52-9 |
2-Propenoic acid, 2-methyl-, methyl ester, polymer with 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl 2-propenoate, block |
|
19 |
93705-98-7 |
2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl ester, polymer with methyl 2-methyl-2-propenoate |
|
20 |
119973-84-1 |
2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluorododecyl ester, polymer with 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl 2-propenoate, .alpha.-(2-methyl-1-oxo-2-propenyl)-.omega.-[(2-methyl-1-oxo-2-propenyl)oxy]poly(oxy-1,2-ethanediyl), 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-nonacosafluorohexadecyl 2-propenoate, octadecyl 2-propenoate and 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl 2-propenoate |
|
21 |
119973-85-2 |
2-Propenoic acid, 2-methyl-, 3-chloro-2-hydroxypropyl ester, polymer with 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluorododecyl 2-propenoate, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl 2-propenoate, N-(hydroxymethyl)-2-propenamide, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-nonacosafluorohexadecyl 2-propenoate, octadecyl 2-propenoate and 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl 2-propenoate |
|
22 |
1094598-90-9 |
2-Propenoic acid, 2-methyl-, 3-chloro-2-hydroxypropyl ester, polymer with 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluorododecyl 2-propenoate, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl 2-propenoate, N-(hydroxymethyl)-2-propenamide, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-nonacosafluorohexadecyl 2-propenoate, octadecyl 2-propenoate, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl 2-propenoate and 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl 2-propenoate |
-
LC-PFCA
-
毒性分類及相關運作規定尚在評估。
-
增列LC-PFCA之111種CAS No.
|
序號 |
CAS No. |
英文名稱 |
|---|---|---|
|
1 |
2920913-30-8 |
Heneicosanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,21,21,21-hentetracontafluoro- |
|
2 |
101896-32-6 |
2-Propenoic acid, 2-methyl-, 3-chloro-2-hydroxypropyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]poly(difluoromethylene) |
|
3 |
110053-43-5 |
Imidodicarbonic diamide, N,N ′,2-tris(6-isocyanatohexyl)-, reaction products with 3-chloro-1,2-propanediol and α-fluoro-ω-(2-hydroxyethyl)poly(difluoromethylene) |
|
4 |
113089-67-1 |
Thiols, C4-20, γ-ω-perfluoro, reaction products with methylated formaldehyde-1,3,5-triazine-2,4,6-triamine polymer |
|
5 |
115340-82-4 |
Betaines, (hydroxyethyl)methyl(γ,ω-perfluoro-C8-14-β-alkenyl)(2-sulfopropyl) |
|
6 |
115535-36-9 |
Quaternary ammonium compounds, trimethyl(δ-ω-perfluoro-C8-14-β-alkenyl), chlorides |
|
7 |
118102-37-7 |
Alcohols, C8-14, γ-ω-perfluoro, reaction products with epichlorohydrin, polyethylene glycol mono-Me ether and N,N ′,2-tris(6-isocyanatohexyl)imidodicarbonic diamide |
|
8 |
118102-38-8 |
Alcohols, C8-14, γ-ω-perfluoro, reaction products with epichlorohydrin, tetrahydrofuran homopolymer and N,N ′,2-tris(6-isocyanatohexyl)imidodicarbonic diamide |
|
9 |
123171-68-6 |
Poly(difluoromethylene), α-[2-(acetyloxy)-3-[(carboxymethyl)dimethylammonio]propyl]-ω-fluoro-, inner salt |
|
10 |
1246542-93-7 |
Alcohols, C16-20-branched, reaction products with 1,6-diisocyanatohexane homopolymer, α-fluoro-ω-(2-hydroxyethyl)poly(difluoromethylene) and stearyl alc.
|
|
11 |
126927-97-7 |
Hexane, 1,6-diisocyanato-, homopolymer, reaction products with α-fluoro-ω-(2-hydroxyethyl)poly(difluoromethylene) |
|
12 |
127133-57-7 |
Quaternary ammonium compounds, diethylmethyl(γ-ω-perfluoro-C8-14-β-alkenyl), Me sulfates |
|
13 |
133921-38-7 |
Nonadecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,19-heptatriacontafluoro- |
|
14 |
141074-63-7 |
Pentadecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,15-nonacosafluoro- |
|
15 |
145477-02-7 |
Quaternary ammonium compounds, diethylmethyl(γ-ω-perfluoro-C8-14-β-alkenyl), tetraphenylborates |
|
16 |
148240-84-0 |
1,3-Propanediol, 2,2-bis[[(γ-ω-perfluoro-C4-10-alkyl)thio]methyl] derivs., phosphates |
|
17 |
148878-17-5 |
2-Propenoic acid, 2-methyl-, C2-18-alkyl esters, polymers with α-fluoro-ω-[2-[(1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene) and vinylidene chloride |
|
18 |
150135-57-2 |
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymers with Bu acrylate, γ-ω-perfluoro-C8-14-alkyl acrylate and polyethylene glycol monomethacrylate, 2,2 ′-(1,2-diazenediyl)bis[2,4-dimethylpentanenitrile]-initiated |
|
19 |
153325-45-2 |
Quaternary ammonium compounds, diethylmethyl(γ-ω-perfluoro-C8-14-β-alkenyl), tetraphenylborates |
|
20 |
15811-52-6 |
Dodecanoyl fluoride, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,12,12,12-docosafluoro-11-(trifluoromethyl)- |
|
21 |
16486-96-7 |
Dodecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,12,12,12-docosafluoro-11-(trifluoromethyl)- |
|
22 |
16517-11-6 |
Octadecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-pentatriacontafluoro- |
|
23 |
174125-96-3 |
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymers with δ-ω-perfluoro-C10-16-alkyl acrylate and vinyl acetate |
|
24 |
178233-67-5 |
2-Propenoic acid, C12-14-alkyl esters, polymers with Bu (1-oxo-2-propenyl)carbamate and δ-ω-perfluoro-C6-12-alkyl acrylate |
|
25 |
178535-23-4 |
Fatty acids, linseed-oil, γ-ω-perfluoro-C8-14-alkyl esters |
|
26 |
18024-09-4 |
Tetradecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,14,14,14-hexacosafluoro-13-(trifluoromethyl)- |
|
27 |
182700-77-2 |
Siloxanes and Silicones, di-Me, hydroxy-terminated, polymers with tetradecanedioic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-tricosafluoro-1-tridecanol-terminated |
|
28 |
185630-70-0 |
Alcohols, C8-14, γ-ω-perfluoro, reaction products with epichlorohydrin and propylene oxide, trimethylamine-quaternized |
|
29 |
196316-34-4 |
2-Propenoic acid, 2-methyl-, 2-(dimethylamino)ethyl ester, polymers with γ-ω-perfluoro-C10-16-alkyl acrylate and vinyl acetate, acetates |
|
30 |
2058-94-8 |
Undecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,11-heneicosafluoro- |
|
31 |
21049-39-8 |
Nonanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-, sodium salt (1:1) |
|
32 |
220237-52-5 |
9-Octadecenoic acid (9Z)-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl ester |
|
33 |
220713-37-1 |
2-Propenoic acid, 2-methyl-, 2-aziridinyl ester, polymer with α-fluoro-ω-[2-[(1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene) and phenylmethyl 2-methyl-2-propenoate |
|
34 |
220713-74-6 |
2-Propenoic acid, 2-methyl-, 2-aziridinyl ester, polymer with α-fluoro-ω-[[(2-methyl-1-oxo-2-propenyl)oxy]methyl]poly(difluoromethylene) and octadecyl 2-methyl-2-propenoate |
|
35 |
220713-85-9 |
2-Propenoic acid, 2-methyl-, 2-aziridinyl ester, polymer with 1,1-dimethylethyl 2-methyl-2-propenoate and α-fluoro-ω-[[(2-methyl-1-oxo-2-propenyl)oxy]methyl]poly(difluoromethylene) |
|
36 |
253682-97-2 |
Butanedioic acid, monopolyisobutylene derivs., 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluoro tetradecyl ester |
|
37 |
253682-98-3 |
Butanedioic acid, monopolyisobutylene derivs., 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heneicosafluorododecyl ester |
|
38 |
253873-70-0 |
Alcohols, C8-14, γ-ω-perfluoro, polymers with 1,6-diisocyanatohexane, ethylene glycol, glycidol and 2,4-TDI |
|
39 |
3108-42-7 |
Decanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro-, ammonium salt (1:1) |
|
40 |
325966-78-7 |
2-Propenoic acid, 2-methyl-, 3-chloro-2-hydroxypropyl ester, polymers with N-(1,1-dimethyl-3-oxobutyl)-2-propenamide, 2-ethylhexyl acrylate, γ-ω-perfluoro-C8-16-alkyl acrylate, stearyl acrylate and vinyl chloride, 2,2 ′-azobis[2-methylpropanimidamide] dihydrochloride-initiated |
|
41 |
329201-80-1 |
Imidodicarbonic diamide, N,N ′,2-tris(6-isocyanatohexyl)-, reaction products with ethylene glycol, α-fluoro-ω-[2-[(1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene), glycidol and 2,4-TDI |
|
42 |
332076-28-5 |
2-Oxepanone, homopolymer, decyl perfluoro-C8-14-alkyl esters, reaction products with 1H-imidazole-1-propanamine, polyethylene-polypropylene glycol and TDI homopolymer |
|
43 |
332076-33-2 |
2-Oxepanone, homopolymer, decyl perfluoro-C8-14-alkyl esters, reaction products with 1H-imidazole-1-propanamine and TDI homopolymer |
|
44 |
332076-34-3 |
2-Oxepanone, homopolymer, decyl perfluoro-C8-14-alkyl esters, reaction products with 1H-imidazole-1-propanamine, polyethylene glycol and TDI homopolymer |
|
45 |
333784-44-4 |
2-Propenoic acid, 2-methyl-, 3-chloro-2-hydroxypropyl ester, polymers with 2,3-dihydroxypropyl methacrylate, γ-ω-perfluoro-C8-16-alkyl acrylate, polyethylene glycol methacrylate Me ether and polypropylene glycol monomethacrylate |
|
46 |
333784-46-6 |
2-Propenoic acid, 2-methyl-, 2-ethylhexyl ester, polymers with maleic anhydride, 2-[[(2-mercaptoethoxy)carbonyl]amino]ethyl methacrylate, γ-ω-perfluoro-C8-16-alkyl acrylate and stearyl methacrylate |
|
47 |
335-76-2 |
Decanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro- |
|
48 |
34395-24-9 |
2-Propenoic acid, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-pentacosafluorotetradecyl ester |
|
49 |
3658-63-7 |
Decanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,10,10,10-octadecafluoro-9-(trifluoromethyl)-, ammonium salt (1:1) |
|
50 |
374928-92-4 |
2-Butenedioic acid (2Z)-, dioctyl ester, polymer with chloroethene and α-fluoro-ω-[2-[(1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene) |
|
51 |
374928-93-5 |
2-Propenenitrile, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene), α-(2-methyl-1-oxo-2-propenyl)-ω-methoxypoly(oxy-1,2-ethanediyl) and α-(2-methyl-1-oxo-2-propenyl)-ω-[(2-methyl-1-oxo-2-propenyl)oxy]poly(oxy-1,2-ethanediyl) |
|
52 |
375-95-1 |
Nonanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro- |
|
53 |
376-06-7 |
Tetradecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-heptacosafluoro- |
|
54 |
376364-33-9 |
Alcohols, C8-14, γ-ω-perfluoro, polymers with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene), methanol, stearyl acrylate, stearyl methacrylate, 2,4-TDI and vinyl chloride |
|
55 |
3793-74-6 |
Dodecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-tricosafluoro-, ammonium salt (1:1) |
|
56 |
3830-45-3 |
Decanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-nonadecafluoro-, sodium salt (1:1) |
|
57 |
4149-60-4 |
Nonanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluoro-, ammonium salt (1:1) |
|
58 |
428842-38-0 |
Hexane, 1,6-diisocyanato-, homopolymer, α-fluoro-ω-(hydroxyethyl)poly(difluoromethylene)- and Me Et ketone oxime- and polyethylene glycol mono-Me ether-blocked |
|
59 |
464178-90-3 |
2-Propen-1-ol, reaction products with 1,1,1,2,2-pentafluoro-2-iodoethane-tetrafluoroethylene telomer, dehydroiodinated, reaction products with epichlorohydrin and triethylenetetramine |
|
60 |
500701-62-2 |
2-Propenoic acid, 2-methyl-, 2-(diethylamino)ethyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene), acetate (salt) |
|
61 |
524729-93-9 |
2-Propenoic acid, polymer with butyl 2-propenoate and 2,5-furandione, γ-ω-perfluoro-C8-14-alkyl esters, potassium salts, tert-Bu benzenecarboperoxoate-initiated |
|
62 |
57475-95-3 |
Heptadecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,17-tritriacontafluoro- |
|
63 |
59493-72-0 |
1-Propanaminium, 3-[[4-[(heptadecafluorononen-1-yl)oxy]benzoyl]amino]-N,N,N-trimethyl-, iodide (1:1) |
|
64 |
59778-97-1 |
2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-tritriacontafluorooctadecyl ester |
|
65 |
65104-65-6 |
1-Eicosanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,20-heptatriacontafluoro- |
|
66 |
65104-66-7 |
2-Propenoic acid, 2-methyl-, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,20-heptatriacontafluoroeicosyl ester |
|
67 |
65104-67-8 |
1-Octadecanol, 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,18-tritriacontafluoro- |
|
68 |
65530-57-6 |
Poly(difluoromethylene), α-fluoro-ω-[2-[[2-(trimethylammonio)ethyl]thio]ethyl]-, methyl sulfate (1:1) |
|
69 |
65530-58-7 |
Poly(difluoromethylene), α-fluoro-ω-(2-hydroxyethyl)-, ester with 2,15-bis(carboxymethyl)-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,2,15,16-tetracarboxylic acid (6:1) |
|
70 |
65530-59-8 |
Poly(difluoromethylene), α-fluoro-ω-(2-hydroxyethyl)-, 2-hydroxy-1,2,3-propanetricarboxylate (3:1) |
|
71 |
65530-61-2 |
Poly(difluoromethylene), α-fluoro-ω-[2-(phosphonooxy)ethyl]- |
|
72 |
65530-63-4 |
Ethanol, 2,2 ′-iminobis-, compd. with α-fluoro-ω-[2-(phosphonooxy)ethyl]poly(difluoromethylene) (2:1) |
|
73 |
65530-64-5 |
Ethanol, 2,2 ′-iminobis-, compd. with α,α′-[phosphinicobis(oxy-2,1-ethanediyl)]bis[ω-fluoropoly(difluoromethylene)] (1:1) |
|
74 |
65530-65-6 |
Poly(difluoromethylene), α-fluoro-ω-[2-[(1-oxooctadecyl)oxy]ethyl]- |
|
75 |
65530-70-3 |
Poly(difluoromethylene), α,α′-[phosphinicobis(oxy-2,1-ethanediyl)]bis[ω-fluoro-, ammonium salt (1:1) |
|
76 |
65530-71-4 |
Poly(difluoromethylene), α-fluoro-ω-[2-(phosphonooxy)ethyl]-, ammonium salt (1:1) |
|
77 |
65530-72-5 |
Poly(difluoromethylene), α-fluoro-ω-[2-(phosphonooxy)ethyl]-, ammonium salt (1:2) |
|
78 |
65530-74-7 |
Ethanol, 2,2 ′-iminobis-, compd. with α-fluoro-ω-[2-(phosphonooxy)ethyl]poly(difluoromethylene) (1:1) |
|
79 |
65530-83-8 |
Poly(difluoromethylene), α-[2-[(2-carboxyethyl)thio]ethyl]-ω-fluoro- |
|
80 |
65605-56-3 |
Poly(difluoromethylene), α-fluoro-ω-(2-hydroxyethyl)-, dihydrogen 2-hydroxy-1,2,3-propanetricarboxylate |
|
81 |
65605-57-4 |
Poly(difluoromethylene), α-fluoro-ω-(2-hydroxyethyl)-, hydrogen 2-hydroxy-1,2,3-propanetricarboxylate |
|
82 |
65605-58-5 |
2-Propenoic acid, 2-methyl-, dodecyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]poly(difluoromethylene) |
|
83 |
65605-59-6 |
2-Propenoic acid, 2-methyl-, dodecyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]poly(difluoromethylene) and N-(hydroxymethyl)-2-propenamide |
|
84 |
65605-60-9 |
2-Propenoic acid, 2-methyl-, dodecyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]poly(difluoromethylene), 2-hydroxyethyl 2-methyl-2-propenoate and N-(hydroxymethyl)-2-propenamide |
|
85 |
65636-35-3 |
Ethanaminium, N,N-diethyl-N-methyl-2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]-, methyl sulfate (1:1), polymer with 2-ethylhexyl 2-methyl-2-propenoate, α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]poly(difluoromethylene), 2-hydroxyethyl 2-methyl-2-propenoate and N-(hydroxymethyl)-2-propenamide |
|
86 |
67905-19-5 |
Hexadecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,16-hentriacontafluoro- |
|
87 |
68015-87-2 |
Dodecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,12,12,12-docosafluoro-11-(trifluoromethyl)-, compd. with ethanamine (1:1) |
|
88 |
68025-62-7 |
Tetradecanoyl fluoride, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,14,14,14-hexacosafluoro-13-(trifluoromethyl)- |
|
89 |
68140-21-6 |
Thiols, C10-20, γ-ω-perfluoro |
|
90 |
68155-54-4 |
2H-Pyran, 2,2,3,3,4,4,5,5,6-nonafluorotetrahydro-6-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-nonadecafluorononyl)- |
|
91 |
68187-25-7 |
Butanoic acid, 4-[[3-(dimethylamino)propyl]amino]-4-oxo-, 2(or 3)-[(γ-ω-perfluoro-C6-20-alkyl)thio] derivs. |
|
92 |
68239-43-0 |
2-Propenoic acid, 2-methyl-, 2-ethylhexyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]poly(difluoromethylene), 2-hydroxyethyl 2-methyl-2-propenoate and N-(hydroxymethyl)-2-propenamide |
|
93 |
68310-12-3 |
Eicosanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,18,18,19,19,20,20,20-nonatriacontafluoro- |
|
94 |
68412-68-0 |
Phosphonic acid, perfluoro-C6-12-alkyl derivs. |
|
95 |
68516-17-6 |
Sulfuric acid, mono(γ-ω-perfluoro-C6-12-alkyl) esters, ammonium salts |
|
96 |
68891-05-4 |
Ethene, tetrafluoro-, homopolymer, α-fluoro-ω-(2-hydroxyethyl)-, citrate, reaction products with 1,6-diisocyanatohexane |
|
97 |
68990-40-9 |
Fatty acids, C18-unsatd., dimers, diisocyanates, polymers with 2,3-bis(γ-ω-perfluoro-C4-18-alkyl)-1,4-butanediol, 1,6-diisocyanato-2,2,4(or 2,4,4)-trimethylhexane and 2,2 ′-(methylimino)bis[ethanol] |
|
98 |
70983-59-4 |
Poly(oxy-1,2-ethanediyl), α-methyl-ω-hydroxy-, 2-hydroxy-3-[(γ-ω-perfluoro-C6-20-alkyl)thio]propyl ethers |
|
99 |
71002-41-0 |
Poly(difluoromethylene), α-[2-(acetyloxy)-2-[(carboxymethyl)dimethylammonio]ethyl]-ω-fluoro-, inner salt |
|
100 |
72629-94-8 |
Tridecanoic acid, 2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-pentacosafluoro- |
|
101 |
74499-44-8 |
Phosphoric acid, γ-ω-perfluoro-C8-16-alkyl esters, compds. with diethanolamine |
|
102 |
84238-62-0 |
Sulfuric acid, mono(γ-ω-perfluoro-C8-12-alkyl) esters, ammonium salts |
|
103 |
92129-34-5 |
Quaternary ammonium compounds, (hydroxyethyl)dimethyl(γ-ω-perfluoro-C8-14-β-alkenyl), Me sulfates (salts) |
|
104 |
93776-16-0 |
1-Pentadecanaminium, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,15-pentacosafluoro-2-hydroxy-N,N-bis(2-hydroxyethyl)-N-methyl-, iodide (1:1) |
|
105 |
93776-17-1 |
1-Tridecanaminium, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,13-heneicosafluoro-2-hydroxy-N,N-bis(2-hydroxyethyl)-N-methyl-, iodide (1:1) |
|
106 |
94095-37-1 |
Pentanoic acid, 4,4-bis[(γ-ω-perfluoro-C6-12-alkyl)thio] derivs., compds. with diethanolamine |
|
107 |
94159-76-9 |
1-Pentadecanaminium, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,15,15,15-tetracosafluoro-2-hydroxy-N,N-bis(2-hydroxyethyl)-N-methyl-14-(trifluoromethyl)-, iodide (1:1) |
|
108 |
94200-42-7 |
1,2-Pentadecanediol, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,15-pentacosafluoro-, 1-(dihydrogen phosphate) |
|
109 |
94200-43-8 |
1,2-Heptadecanediol, 4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,15,15,16,16,17,17,17-nonacosafluoro-, 1-(dihydrogen phosphate) |
|
110 |
97136-02-2 |
2-Propenoic acid, 2-methyl-, 2-ethylhexyl ester, polymer with α-fluoro-ω-[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl]poly(difluoromethylene) |
|
111 |
98219-29-5 |
Betaines, N-(hydroxyethyl)-N-methyl-N-(2-sulfoethyl)-N-(1,1,2-trihydroperfluoro-C8-14-2-alkenyl) |
替代物質建議
- 評估公告全氟己烷磺酸(PFHxS)物質清單具有33個化學物質，透過ZeroPM(Zero Pollution of Persistent, Mobile Substances)資料集查詢，評估公告清單中有3種PFHxS可於該資料集查詢到安全物質進行替代，對照到3種工業用途後，共查詢到31個候選安全替代物質。
- 評估公告全氟辛酸(PFOA)物質清單具有22個化學物質，運用SAS模組系統，對照2種工業用途後，共查詢到18個候選安全替代物質。
- 評估公告長鏈全氟羧酸(LC-PFCA)物質清單具有111個化學物質，透過SAS模組系統及ZeroPM資料集，查詢安全替代物質。運用SAS模組系統，對照 6 個工業用途後，共查詢到3,032個候選替代物質；另透過ZeroPM資料集，評估公告清單中有21種LC-PFCA可於該資料集查詢到安全物質進行替代，對照到9種工業用途後，共查詢到546個候選安全替代物質。
- 相關安全替代物質資訊可至SAS平臺( https://sas.cmdm.tw/ )或ZeroPM(https://zeropm.eu/alternative-assessment-database/ )查詢。
聯絡資訊
CHAMOENV@moenv.gov.tw
